【AEM】空气等离子体活化金属-氰化物框架中催化位点以实现高效的氧气放出反应
定制设计的高性能、低成本电催化剂对于有效的能量转换和储存至关重要。提高非均相催化剂性能的一般指导原则是构建具有高反应性和稳定性的高密度催化位点。金属有机骨架(MOFs)含有高度分散的金属位点,具有良好的键合和电荷状态,旨在以高选择性和高效率催化特定反应。为了保持催化框架的优势,必须在不破坏框架的情况下实现金属位点的修饰。然而,金属位点的选择性,非破坏性修饰是极具挑战性的,因为金属位点上的大多数化学修饰影响了金属-配体键合,这使得框架更易受到损害。
近日,在北京大学李星国教授和郑捷副教授(共同通讯作者)课题组的带领下,与澳大利亚昆士兰科技大学合作,报道了通过使用低温空气等离子体实现框架中金属位点的无损激活。低温空气等离子体含有高活性氧,包括处于激发态的原子氧和分子氧。重要的是,这些活性物质是非热的。高化学反应性和低热效应的组合允许金属位点的选择性修饰而不损坏框架结构。本研究的框架是由氰化物桥联的Fe和Co阳离子组成的Fe /Co双金属氰化物骨架,由低温-空气等离子体产生的高活性氧类通过与金属位点的氧键活化Co-PBA中用于OER的金属位点。基于框架的OER催化剂的特点是在100 mA cm-2的高电流密度下,只有330 mV的极低过电位,这归因于框架中高密度的活性位点。相关成果以题为“Air Plasma Activation of Catalytic Sites in a Metal-Cyanide Framework for Efficient Oxygen Evolution Reaction”发表在了Adv. Energy Mater.上。
图1 等离子体处理Co-PBA的示意图
图2原始和等离子体处理的Co-PBA的微观表征
图3 等离子体处理的Co-PBA的光谱表征
图4 等离子体处理的Co-PBA的结构
图5 等离子体处理的Co-PBA的电化学性能表征
相关内容以“Air Plasma Activation of Catalytic Sites in a Metal-Cyanide Framework for Efficient Oxygen Evolution Reaction”为题,第一作者是郭妍如。在《Adv. Energy Mater.》上发表。
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title | '【AEM】空气等离子体活化金属-氰化物框架中催化位点以实现高效的氧气放出反应' |
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description | '【AEM】空气等离子体活化金属-氰化物框架中催化位点以实现高效的氧气放出反应 定制设计的高性能、低成本电催化剂对于有效的能量转换和储存至关重要。提高非均相催化剂性能的一般指导原则是构建具有高反应' |
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content | '<section powered-by="xiumi.us"> <section> <section> <p>【AEM】空气等离子体活化金属-氰化物框架中催化位点以实现高效的氧气放出反应</p> </section> </section> </section> <section powered-by="xiumi.us"> <section> <section> <p> </p> <p> 定制设计的高性能、低成本电催化剂对于有效的能量转换和储存至关重要。提高非均相催化剂性能的一般指导原则是构建具有高反应性和稳定性的高密度催化位点。金属有机骨架(MOFs)含有高度分散的金属位点,具有良好的键合和电荷状态,旨在以高选择性和高效率催化特定反应。为了保持催化框架的优势,必须在不破坏框架的情况下实现金属位点的修饰。然而,金属位点的选择性,非破坏性修饰是极具挑战性的,因为金属位点上的大多数化学修饰影响了金属-配体键合,这使得框架更易受到损害。</p> </section> </section> </section> <section powered-by="xiumi.us"> <section> <section> <p>近日,在北京大学李星国教授和郑捷副教授(共同通讯作者)课题组的带领下,与澳大利亚昆士兰科技大学合作,报道了通过使用低温空气等离子体实现框架中金属位点的无损激活。低温空气等离子体含有高活性氧,包括处于激发态的原子氧和分子氧。重要的是,这些活性物质是非热的。高化学反应性和低热效应的组合允许金属位点的选择性修饰而不损坏框架结构。本研究的框架是由氰化物桥联的Fe和Co阳离子组成的Fe /Co双金属氰化物骨架,由低温-空气等离子体产生的高活性氧类通过与金属位点的氧键活化Co-PBA中用于OER的金属位点。基于框架的OER催化剂的特点是在100 mA cm-2的高电流密度下,只有330 mV的极低过电位,这归因于框架中高密度的活性位点。相关成果以题为“Air Plasma Activation of Catalytic Sites in a Metal-Cyanide Framework for Efficient Oxygen Evolution Reaction”发表在了Adv. Energy Mater.上。</p> </section> </section> </section> <section powered-by="xiumi.us"> <section> <section><img alt="" src="https://img.ruilang.cn/psmplasma.com/uploadfile/201908/9abd65b6d038a69.jpg" style="width: 278px; height: 208px;" /></section> </section> </section> <section powered-by="xiumi.us"> <section> <section> <p>图1 等离子体处理Co-PBA的示意图</p> </section> </section> </section> <section powered-by="xiumi.us"> <section> <section><img alt="" src="https://img.ruilang.cn/psmplasma.com/uploadfile/201908/be5bc137e81ca3c.jpg" style="width: 278px; height: 208px;" /></section> </section> </section> <section powered-by="xiumi.us"> <section> <section> <p>图2原始和等离子体处理的Co-PBA的微观表征</p> </section> </section> </section> <section powered-by="xiumi.us"> <section> <section><img alt="" src="https://img.ruilang.cn/psmplasma.com/uploadfile/201908/551536b89db5202.jpg" style="width: 278px; height: 208px;" /></section> </section> </section> <section powered-by="xiumi.us"> <section> <section> <p>图3 等离子体处理的Co-PBA的光谱表征</p> </section> </section> </section> <section powered-by="xiumi.us"> <section> <section><img alt="" src="https://img.ruilang.cn/psmplasma.com/uploadfile/201908/e22ace4a41a3b8a.jpg" style="width: 278px; height: 208px;" /></section> </section> </section> <section powered-by="xiumi.us"> <section> <section> <p>图4 等离子体处理的Co-PBA的结构</p> </section> </section> </section> <section powered-by="xiumi.us"> <section> <section><img alt="" src="https://img.ruilang.cn/psmplasma.com/uploadfile/201908/124ae106b3a6dc3.jpg" style="width: 278px; height: 208px;" /></section> </section> </section> <section powered-by="xiumi.us"> <section> <section> <p>图5 等离子体处理的Co-PBA的电化学性能表征</p> </section> </section> </section> <section powered-by="xiumi.us"> <section> <section> <p> </p> <p>相关内容以“Air Plasma Activation of Catalytic Sites in a Metal-Cyanide Framework for Efficient Oxygen Evolution Reaction”为题,第一作者是郭妍如。在《Adv. Energy Mater.》上发表。</p> </section> </section> </section> ' |
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meta_keywords | '' |
meta_description | '【AEM】空气等离子体活化金属-氰化物框架中催化位点以实现高效的氧气放出反应 定制设计的高性能、低成本电催化剂对于有效的能量转换和储存至关重要。提高非均相催化剂性能的一般指导原则是构建具有高反应' |
cat | array ( 'id' => '22', 'tid' => '1', 'pid' => '20', 'mid' => 'news', 'pids' => '0,20', 'name' => '行业动态', 'dirname' => 'industrytrends', 'pdirname' => 'news/', 'child' => '0', 'childids' => '22', 'domain' => NULL, 'mobile_domain' => NULL, 'thumb' => '4', 'show' => '1', 'content' => '', 'setting' => array ( 'disabled' => '0', 'linkurl' => '', 'urlrule' => 1, 'seo' => array ( 'list_title' => '[第{page}页{join}]{catpname}{join}{modname}{join}{SITE_NAME}', 'list_keywords' => '', 'list_description' => '', ), 'template' => array ( 'pagesize' => '12', 'mpagesize' => '12', 'page' => 'page.html', 'list' => 'list.html', 'category' => 'category.html', 'search' => 'search.html', 'show' => 'show.html', ), 'cat_field' => '', 'module_field' => '', 'html' => 0, 'chtml' => 0, ), 'displayorder' => '0', 'scontent' => '', 'scentent' => NULL, 'sname' => NULL, 'disabled' => '0', 'ismain' => '0', 'duotu' => array ( ), 'wenben' => array ( ), 'scontent2' => NULL, 'scontent3' => NULL, 'channelicon' => '/Upload/icon/hyxw.png', 'channelalbum' => array ( 0 => array ( 'url' => '/uploadfile/nopic', 'file' => 'nopic', 'title' => '', 'description' => '', ), ), 'topid' => '20', 'pcatpost' => 0, 'catids' => array ( 0 => '22', ), 'is_post' => 1, 'url' => 'http://www.psmplasma.com/industrytrends.html', 'total' => '-', '_duotu' => NULL, '_wenben' => NULL, '_channelalbum' => '{"file":["nopic"],"title":[""],"description":[""]}', 'field' => array ( ), ) |
top | array ( 'id' => '20', 'tid' => '1', 'pid' => '0', 'mid' => 'news', 'pids' => '0', 'name' => '新闻中心', 'dirname' => 'news', 'pdirname' => '', 'child' => '1', 'childids' => '20,21,22', 'domain' => NULL, 'mobile_domain' => NULL, 'thumb' => '', 'show' => '1', 'content' => '', 'setting' => array ( 'disabled' => '0', 'linkurl' => '', 'urlrule' => 1, 'seo' => array ( 'list_title' => '[第{page}页{join}]{catpname}{join}{modname}{join}{SITE_NAME}', 'list_keywords' => '', 'list_description' => '', ), 'template' => array ( 'pagesize' => '12', 'mpagesize' => '12', 'page' => 'page.html', 'list' => 'list.html', 'category' => 'category.html', 'search' => 'search.html', 'show' => 'show.html', ), 'cat_field' => '', 'module_field' => '', 'html' => 0, 'chtml' => 0, ), 'displayorder' => '4', 'scontent' => '关注新闻时讯,坚持与时俱进', 'scentent' => NULL, 'sname' => NULL, 'disabled' => '0', 'ismain' => '1', 'duotu' => array ( ), 'wenben' => array ( ), 'scontent2' => NULL, 'scontent3' => NULL, 'channelicon' => '/Upload/icon/20.jpg', 'channelalbum' => array ( 0 => array ( 'url' => '/uploadfile/nopic', 'file' => 'nopic', 'title' => '', 'description' => '', ), ), 'topid' => '20', 'pcatpost' => 0, 'catids' => array ( 0 => '20', 1 => '21', 2 => '22', ), 'is_post' => 0, 'url' => 'http://www.psmplasma.com/news.html', 'total' => '-', '_duotu' => NULL, '_wenben' => NULL, '_channelalbum' => '{"file":["nopic"],"title":[""],"description":[""]}', 'field' => array ( ), ) |
pageid | 1 |
params | array ( 'catid' => '22', ) |
parent | array ( 'id' => '20', 'tid' => '1', 'pid' => '0', 'mid' => 'news', 'pids' => '0', 'name' => '新闻中心', 'dirname' => 'news', 'pdirname' => '', 'child' => '1', 'childids' => '20,21,22', 'domain' => NULL, 'mobile_domain' => NULL, 'thumb' => '', 'show' => '1', 'content' => '', 'setting' => array ( 'disabled' => '0', 'linkurl' => '', 'urlrule' => 1, 'seo' => array ( 'list_title' => '[第{page}页{join}]{catpname}{join}{modname}{join}{SITE_NAME}', 'list_keywords' => '', 'list_description' => '', ), 'template' => array ( 'pagesize' => '12', 'mpagesize' => '12', 'page' => 'page.html', 'list' => 'list.html', 'category' => 'category.html', 'search' => 'search.html', 'show' => 'show.html', ), 'cat_field' => '', 'module_field' => '', 'html' => 0, 'chtml' => 0, ), 'displayorder' => '4', 'scontent' => '关注新闻时讯,坚持与时俱进', 'scentent' => NULL, 'sname' => NULL, 'disabled' => '0', 'ismain' => '1', 'duotu' => array ( ), 'wenben' => array ( ), 'scontent2' => NULL, 'scontent3' => NULL, 'channelicon' => '/Upload/icon/20.jpg', 'channelalbum' => array ( 0 => array ( 'url' => '/uploadfile/nopic', 'file' => 'nopic', 'title' => '', 'description' => '', ), ), 'topid' => '20', 'pcatpost' => 0, 'catids' => array ( 0 => '20', 1 => '21', 2 => '22', ), 'is_post' => 0, 'url' => 'http://www.psmplasma.com/news.html', 'total' => '-', '_duotu' => NULL, '_wenben' => NULL, '_channelalbum' => '{"file":["nopic"],"title":[""],"description":[""]}', 'field' => array ( ), ) |
related | array ( 21 => array ( 'id' => '21', 'tid' => '1', 'pid' => '20', 'mid' => 'news', 'pids' => '0,20', 'name' => '公司新闻', 'dirname' => 'companynews', 'pdirname' => 'news/', 'child' => '0', 'childids' => '21', 'domain' => NULL, 'mobile_domain' => NULL, 'thumb' => '3', 'show' => '1', 'content' => '', 'setting' => array ( 'disabled' => '0', 'linkurl' => '', 'urlrule' => 1, 'seo' => array ( 'list_title' => '[第{page}页{join}]{catpname}{join}{modname}{join}{SITE_NAME}', 'list_keywords' => '', 'list_description' => '', ), 'template' => array ( 'pagesize' => '12', 'mpagesize' => '12', 'page' => 'page.html', 'list' => 'list.html', 'category' => 'category.html', 'search' => 'search.html', 'show' => 'show.html', ), 'cat_field' => '', 'module_field' => '', 'html' => 0, 'chtml' => 0, ), 'displayorder' => '0', 'scontent' => '', 'scentent' => NULL, 'sname' => NULL, 'disabled' => '0', 'ismain' => '0', 'duotu' => array ( ), 'wenben' => array ( ), 'scontent2' => NULL, 'scontent3' => NULL, 'channelicon' => '/Upload/icon/gsxw.png', 'channelalbum' => array ( 0 => array ( 'url' => '/uploadfile/nopic', 'file' => 'nopic', 'title' => '', 'description' => '', ), ), 'topid' => '20', 'pcatpost' => 0, 'catids' => array ( 0 => '21', ), 'is_post' => 1, 'url' => 'http://www.psmplasma.com/companynews.html', 'total' => '-', '_duotu' => NULL, '_wenben' => NULL, '_channelalbum' => '{"file":["nopic"],"title":[""],"description":[""]}', 'field' => array ( ), ), 22 => array ( 'id' => '22', 'tid' => '1', 'pid' => '20', 'mid' => 'news', 'pids' => '0,20', 'name' => '行业动态', 'dirname' => 'industrytrends', 'pdirname' => 'news/', 'child' => '0', 'childids' => '22', 'domain' => NULL, 'mobile_domain' => NULL, 'thumb' => '4', 'show' => '1', 'content' => '', 'setting' => array ( 'disabled' => '0', 'linkurl' => '', 'urlrule' => 1, 'seo' => array ( 'list_title' => '[第{page}页{join}]{catpname}{join}{modname}{join}{SITE_NAME}', 'list_keywords' => '', 'list_description' => '', ), 'template' => array ( 'pagesize' => '12', 'mpagesize' => '12', 'page' => 'page.html', 'list' => 'list.html', 'category' => 'category.html', 'search' => 'search.html', 'show' => 'show.html', ), 'cat_field' => '', 'module_field' => '', 'html' => 0, 'chtml' => 0, ), 'displayorder' => '0', 'scontent' => '', 'scentent' => NULL, 'sname' => NULL, 'disabled' => '0', 'ismain' => '0', 'duotu' => array ( ), 'wenben' => array ( ), 'scontent2' => NULL, 'scontent3' => NULL, 'channelicon' => '/Upload/icon/hyxw.png', 'channelalbum' => array ( 0 => array ( 'url' => '/uploadfile/nopic', 'file' => 'nopic', 'title' => '', 'description' => '', ), ), 'topid' => '20', 'pcatpost' => 0, 'catids' => array ( 0 => '22', ), 'is_post' => 1, 'url' => 'http://www.psmplasma.com/industrytrends.html', 'total' => '-', '_duotu' => NULL, '_wenben' => NULL, '_channelalbum' => '{"file":["nopic"],"title":[""],"description":[""]}', 'field' => array ( ), ), ) |
urlrule | '/news/industrytrends/332-[page].html' |
fix_html_now_url | '' |
my_web_url | 'http://psmplasma.com/index.php?c=show&id=332' |
get | array ( 'c' => 'show', 'id' => '332', ) |
ys_tpl | array ( 'company' => '深圳市普仕曼科技有限公司', 'contact' => '杨先生', 'telephone' => '0755-27204347', 'mobile' => '13923479129&13510685447', 'email' => 'edward.yang@psmplasma.com', 'erweima' => '659', 'postcode' => '518054', 'address' => '深圳市宝安区沙井街道大王山工业一路2号六层', 'T1' => '23', 'T2' => '32', 'T3' => '15', 'T4' => '20', 'T5' => '57', 'T7' => '23', 'nText' => '<h2 style="font-weight:bold;font-size:28px;">普仕曼科技</h2><p style="font-size:14px">专注等离子体表面处理设备</p><p> </p><p style="font-size:18px">质量为根本<br/>市场为导向<br/>人才为核心</p>', 'M2' => '23', 'M3' => '31', 'ditubiaozhu' => '113.811818,22.717887', 'tianditukey' => '55f4dc93d4b791534be8342cbe7440ca ', ) |
ys_tpl1 | array ( 'company' => '公司名称', 'contact' => '联系人', 'telephone' => '联系电话', 'mobile' => '手机', 'email' => '邮箱', 'erweima' => '二维码', 'postcode' => '邮编', 'address' => '联系地址', 'T1' => '产品', 'T2' => '应用', 'T3' => '关于', 'T4' => '新闻', 'T5' => '伙伴', 'T7' => '内页默认导航', 'nText' => '内页右侧富文本', 'M2' => '手机导航1', 'M3' => '手机导航2', 'ditubiaozhu' => '地图标注', 'tianditukey' => '天地图key', ) |
cache.php | /www/rl/psmplasma.com/cache/config/cache.php |
domain_app.php | /www/rl/psmplasma.com/cache/config/domain_app.php |
domain_client.php | /www/rl/psmplasma.com/cache/config/domain_client.php |
site.php | /www/rl/psmplasma.com/cache/config/site.php |
system.php | /www/rl/psmplasma.com/cache/config/system.php |
_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_footer.html.cache.php | /www/rl/psmplasma.com/cache/template/_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_footer.html.cache.php |
_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_header.html.cache.php | /www/rl/psmplasma.com/cache/template/_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_header.html.cache.php |
_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_location.html.cache.php | /www/rl/psmplasma.com/cache/template/_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_location.html.cache.php |
_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_show.html.cache.php | /www/rl/psmplasma.com/cache/template/_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_show.html.cache.php |
_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_subchannel.html.cache.php | /www/rl/psmplasma.com/cache/template/_DS_www_DS_rl_DS_psmplasma.com_DS_template_DS_pc_DS_psmplasma_DS_home_DS_subchannel.html.cache.php |
custom.php | /www/rl/psmplasma.com/config/custom.php |
database.php | /www/rl/psmplasma.com/config/database.php |
hooks.php | /www/rl/psmplasma.com/config/hooks.php |
Auto.php | /www/rl/psmplasma.com/dayrui/App/Form/Config/Auto.php |
Category.php | /www/rl/psmplasma.com/dayrui/App/Module/Action/Category.php |
Auto.php | /www/rl/psmplasma.com/dayrui/App/Module/Config/Auto.php |
Filters.php | /www/rl/psmplasma.com/dayrui/App/Module/Config/Filters.php |
Hooks.php | /www/rl/psmplasma.com/dayrui/App/Module/Config/Hooks.php |
Module_init.php | /www/rl/psmplasma.com/dayrui/App/Module/Config/Module_init.php |
Run.php | /www/rl/psmplasma.com/dayrui/App/Module/Config/Run.php |
Module.php | /www/rl/psmplasma.com/dayrui/App/Module/Extends/Home/Module.php |
Category.php | /www/rl/psmplasma.com/dayrui/App/Module/Libraries/Category.php |
Content.php | /www/rl/psmplasma.com/dayrui/App/Module/Models/Content.php |
Hooks.php | /www/rl/psmplasma.com/dayrui/App/Myinit/Config/Hooks.php |
Hooks.php | /www/rl/psmplasma.com/dayrui/App/Ys_tpl/Config/Hooks.php |
App.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/App.php |
Autoload.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Autoload.php |
Cache.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Cache.php |
Constants.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Constants.php |
ContentSecurityPolicy.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/ContentSecurityPolicy.php |
Cookie.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Cookie.php |
Database.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Database.php |
Events.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Events.php |
Exceptions.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Exceptions.php |
Feature.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Feature.php |
Filters.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Filters.php |
Kint.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Kint.php |
Logger.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Logger.php |
Modules.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Modules.php |
Routes.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Routes.php |
Routing.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Routing.php |
Services.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Services.php |
Toolbar.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/Toolbar.php |
UserAgents.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Config/UserAgents.php |
Cache.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/Cache.php |
CodeIgniter.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/CodeIgniter.php |
Controller.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/Controller.php |
Exceptions.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/Exceptions.php |
Hook.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/Hook.php |
Model.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/Model.php |
Request.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/Request.php |
Routes.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/Routes.php |
View.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Extend/View.php |
Init.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/Init.php |
ResponseTrait.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/API/ResponseTrait.php |
Autoloader.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Autoloader/Autoloader.php |
FileLocator.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Autoloader/FileLocator.php |
CacheFactory.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cache/CacheFactory.php |
CacheInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cache/CacheInterface.php |
BaseHandler.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cache/Handlers/BaseHandler.php |
FileHandler.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cache/Handlers/FileHandler.php |
ResponseCache.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cache/ResponseCache.php |
CodeIgniter.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/CodeIgniter.php |
Common.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Common.php |
AutoloadConfig.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/AutoloadConfig.php |
BaseConfig.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/BaseConfig.php |
BaseService.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/BaseService.php |
Config.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/Config.php |
DotEnv.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/DotEnv.php |
Factories.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/Factories.php |
Factory.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/Factory.php |
Routes.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/Routes.php |
Routing.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/Routing.php |
Services.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Config/Services.php |
Controller.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Controller.php |
CloneableCookieInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cookie/CloneableCookieInterface.php |
Cookie.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cookie/Cookie.php |
CookieInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cookie/CookieInterface.php |
CookieStore.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Cookie/CookieStore.php |
BaseBuilder.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/BaseBuilder.php |
BaseConnection.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/BaseConnection.php |
BaseResult.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/BaseResult.php |
Config.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/Config.php |
ConnectionInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/ConnectionInterface.php |
Database.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/Database.php |
Builder.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/MySQLi/Builder.php |
Connection.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/MySQLi/Connection.php |
Result.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/MySQLi/Result.php |
Query.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/Query.php |
QueryInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/QueryInterface.php |
ResultInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Database/ResultInterface.php |
Exceptions.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Exceptions.php |
Timer.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Timer.php |
Toolbar.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar.php |
BaseCollector.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar/Collectors/BaseCollector.php |
Database.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar/Collectors/Database.php |
Events.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar/Collectors/Events.php |
Files.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar/Collectors/Files.php |
Logs.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar/Collectors/Logs.php |
Routes.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar/Collectors/Routes.php |
Timers.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar/Collectors/Timers.php |
Views.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Debug/Toolbar/Collectors/Views.php |
Events.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Events/Events.php |
DebugToolbar.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Filters/DebugToolbar.php |
FilterInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Filters/FilterInterface.php |
Filters.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Filters/Filters.php |
ContentSecurityPolicy.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/ContentSecurityPolicy.php |
Header.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/Header.php |
IncomingRequest.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/IncomingRequest.php |
Message.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/Message.php |
MessageInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/MessageInterface.php |
MessageTrait.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/MessageTrait.php |
OutgoingRequest.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/OutgoingRequest.php |
OutgoingRequestInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/OutgoingRequestInterface.php |
Request.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/Request.php |
RequestInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/RequestInterface.php |
RequestTrait.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/RequestTrait.php |
Response.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/Response.php |
ResponseInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/ResponseInterface.php |
ResponseTrait.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/ResponseTrait.php |
SiteURI.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/SiteURI.php |
SiteURIFactory.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/SiteURIFactory.php |
URI.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/URI.php |
UserAgent.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/HTTP/UserAgent.php |
array_helper.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Helpers/array_helper.php |
kint_helper.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Helpers/kint_helper.php |
url_helper.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Helpers/url_helper.php |
Time.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/I18n/Time.php |
TimeTrait.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/I18n/TimeTrait.php |
Logger.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Log/Logger.php |
Modules.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Modules/Modules.php |
AutoRouter.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Router/AutoRouter.php |
AutoRouterInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Router/AutoRouterInterface.php |
RouteCollection.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Router/RouteCollection.php |
RouteCollectionInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Router/RouteCollectionInterface.php |
Router.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Router/Router.php |
RouterInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Router/RouterInterface.php |
Superglobals.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Superglobals.php |
Escaper.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Escaper/Escaper.php |
FacadeInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/FacadeInterface.php |
Kint.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/Kint.php |
AbstractRenderer.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/Renderer/AbstractRenderer.php |
CliRenderer.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/Renderer/CliRenderer.php |
RendererInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/Renderer/RendererInterface.php |
RichRenderer.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/Renderer/RichRenderer.php |
TextRenderer.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/Renderer/TextRenderer.php |
Utils.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/Utils.php |
init.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/init.php |
init_helpers.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/Kint/init_helpers.php |
LogLevel.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/PSR/Log/LogLevel.php |
LoggerInterface.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/ThirdParty/PSR/Log/LoggerInterface.php |
ConditionalTrait.php | /www/rl/psmplasma.com/dayrui/CodeIgniter/System/Traits/ConditionalTrait.php |
Show.php | /www/rl/psmplasma.com/dayrui/Fcms/Control/Show.php |
Helper.php | /www/rl/psmplasma.com/dayrui/Fcms/Core/Helper.php |
Hooks.php | /www/rl/psmplasma.com/dayrui/Fcms/Core/Hooks.php |
Model.php | /www/rl/psmplasma.com/dayrui/Fcms/Core/Model.php |
Phpcmf.php | /www/rl/psmplasma.com/dayrui/Fcms/Core/Phpcmf.php |
Service.php | /www/rl/psmplasma.com/dayrui/Fcms/Core/Service.php |
View.php | /www/rl/psmplasma.com/dayrui/Fcms/Core/View.php |
Date.php | /www/rl/psmplasma.com/dayrui/Fcms/Field/Date.php |
File.php | /www/rl/psmplasma.com/dayrui/Fcms/Field/File.php |
Text.php | /www/rl/psmplasma.com/dayrui/Fcms/Field/Text.php |
Textarea.php | /www/rl/psmplasma.com/dayrui/Fcms/Field/Textarea.php |
Ueditor.php | /www/rl/psmplasma.com/dayrui/Fcms/Field/Ueditor.php |
Init.php | /www/rl/psmplasma.com/dayrui/Fcms/Init.php |
Cache.php | /www/rl/psmplasma.com/dayrui/Fcms/Library/Cache.php |
Field.php | /www/rl/psmplasma.com/dayrui/Fcms/Library/Field.php |
Input.php | /www/rl/psmplasma.com/dayrui/Fcms/Library/Input.php |
Lang.php | /www/rl/psmplasma.com/dayrui/Fcms/Library/Lang.php |
Router.php | /www/rl/psmplasma.com/dayrui/Fcms/Library/Router.php |
Security.php | /www/rl/psmplasma.com/dayrui/Fcms/Library/Security.php |
Seo.php | /www/rl/psmplasma.com/dayrui/Fcms/Library/Seo.php |
Content.php | /www/rl/psmplasma.com/dayrui/Fcms/Model/Content.php |
Member.php | /www/rl/psmplasma.com/dayrui/Fcms/Model/Member.php |
Version.php | /www/rl/psmplasma.com/dayrui/My/Config/Version.php |
lang.php | /www/rl/psmplasma.com/wwwroot/api/language/zh-cn/lang.php |
index.php | /www/rl/psmplasma.com/wwwroot/index.php |
File: | /www/rl/psmplasma.com/dayrui/Fcms/Control/Show.php |
App: | / |
Controller: | show |
Method: | index |
URI: | show/index |
URL: | http://psmplasma.com/index.php?c=show&id=332 |
Time | Event Name | Times Called |
---|---|---|
9.65 ms | pre_system | 1 |
0.16 ms | dbquery | 5 |
Action | Datetime | Status | Method | URL | Content-Type | Is AJAX? |
---|---|---|---|---|---|---|
2025-05-06 08:17:55.057848 | 200 | GET | http://psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:17:31.257263 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:15:21.485233 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:15:17.813669 | 200 | GET | http://www.psmplasma.com/index.php/cyspdlzpq.html | text/html; charset=UTF-8 | No | |
2025-05-06 08:13:59.342456 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:11:55.446853 | 200 | GET | http://psmplasma.com/index.php/ | text/html; charset=UTF-8 | No | |
2025-05-06 08:11:17.559419 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:11:02.667177 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:10:55.970398 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:09:18.265214 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:07:18.044371 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:06:02.244593 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:03:00.242684 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:02:47.570871 | 200 | GET | http://www.psmplasma.com/index.php/ | text/html; charset=UTF-8 | No | |
2025-05-06 08:02:29.003895 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 08:01:34.777531 | 200 | GET | http://www.psmplasma.com/index.php/industrytrends/443.html | text/html; charset=UTF-8 | No | |
2025-05-06 07:59:16.727774 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 07:58:25.422082 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 07:58:22.042369 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No | |
2025-05-06 07:58:18.876402 | 200 | GET | http://www.psmplasma.com/index.php | text/html; charset=UTF-8 | No |
Session doesn't seem to be active.
c | show |
id | 332 |
Accept-Encoding | gzip, deflate |
Accept | text/html,application/xhtml+xml,application/xml;q=0.9,image/avif,image/webp,image/apng,*/*;q=0.8,application/signed-exchange;v=b3;q=0.7 |
User-Agent | Mozilla/5.0 AppleWebKit/537.36 (KHTML, like Gecko; compatible; ClaudeBot/1.0; +claudebot@anthropic.com) |
Upgrade-Insecure-Requests | 1 |
Cache-Control | no-cache |
Pragma | no-cache |
Connection | keep-alive |
Host | psmplasma.com |
Cache-Control | no-store, max-age=0, no-cache |
Content-Type | text/html; charset=UTF-8 |
CodeIgniter Version: | 4.4.3 |
PHP Version: | 8.0.26 |
PHP SAPI: | fpm-fcgi |
Environment: | |
Base URL: | http://psmplasma.com/ |
Timezone: | PRC |
Locale: | zh-cn |
Content Security Policy Enabled: | No |